The reported toxicity of oxybenzone-based sunscreens to corals has raised concerns about the impacts of ecotourist-shed sunscreens on corals already weakened by global stressors. Benzophenone is a known carcinogen and endocrine disruptor. Marine Sanctuaries are home to some of the ocean's most biologically diverse and culturally significant marine areas, and we need to ensure that these critical areas are protected from harmful chemicals, in addition to other damaging practices like oil and gas extraction Benzophenone is persistent, bioaccumulative and toxic (PBT). Benzophenone-3 (BP-3) belongs to the organic sunscreens, which are widely used in personal care and cosmetic products. Benzophenone-3, or oxybenzone, primarily functions as a photostabilizer and sunscreen. When used in OTC sunscreen drug products, Benzophenone-8 must be called Dioxybenzone. The main usage of this medicine is prevention and protection from sunburn. Benzophenone is the organic compound. 2006; National Library of Medicine 2007; Rastogi 2002).BP-3 also has been used as ultraviolet stabilizer in plastic surface coatings for food packaging to prevent polymer or food . See Sunscreen Article. For this reason, it is produced for use as sunscreen in lotions, conditioners, and cosmetics. Both octocrylene and benzophenone are readily absorbed into the skin. Our client Dr. Anthony Held filed a complaint against L'Oreal USA, Inc. yesterday in Marin County Superior Court alleging that benzophenone is present in sunscreens manufactured, distributed, and offered for sale or use to consumers throughout the State of California, without the requisite health hazard warnings. Benzophenone & Related Compounds Benzophenone is used in personal care products such as lip balm and nail polish to protect the products from UV light. The hormone plays a key role in the health of women, and disrupting it can lead to early puberty . Consumer Reports shared that up to 6,000 tons of sunscreen are estimated to wash into coral reefs around the globe each year. In . Benzophenone is a chemical with a sweet floral smell. Scientists have used a mouse study to explore the effects diet and the chemical benzophenone-3 have on breast cancer risk. The reason why patients photosensitized to the drug ketoprofen (KP) may develop severe photoallergic skin reactions to octocrylene (OCT), an organic ultraviolet filter in sunscreens and cosmetics, remains largely unknown. Benzophenone, a common ingredient in sunscreen, has been proven as a carcinogen (cancer-causing agent) in animals. BP-3 absorbs and scatters the sun's harmful ultraviolet (UV) rays. It falls in the category of benzene derivative called benzhydryl compounds. Octocrylene naturally degrades into the chemical, benzophenone, in over a dozen popular products, as demonstrated in a study published in the journal, Chemical Research in Toxicology, by French and . Benzophenone-3 (BP-3) is a naturally occurring chemical found in some flowering plants. Comment on Benzophenone Accumulates over Time from the Degradation of Octocrylene in Commercial Sunscreen Products Chem Res Toxicol . In addition to causing sunburn, UV radiation is a significant cause of premature aging of the skin and contributes to the development of melanoma and other forms of skin cancer. 2004; 123 (1):57-61. Benzophenone | C6H5COC6H5 - PubChem compound Summary Benzophenone Contents 1 Structures 2 Names and Identifiers 3 Chemical and Physical Properties 4 Spectral Information 5 Related Records 6 Chemical Vendors 7 Drug and Medication Information 8 Food Additives and Ingredients 9 Pharmacology and Biochemistry 10 Use and Manufacturing 11 Identification Research shows that benzophenone in sunscreens can interfere with estrogen, according to the WHO. Benzophenone is a different chemical than benzophenone-3 (also called oxybenzone) and benzophenone-4 (also called sulisobenzone). Its presence in food products or food packaging is banned in the United States. Octocrylene is a widely used chemical sunscreen that absorbs UV in both the UVB and UVA portions of the solar spectrum. Though it covers UVB and short UVA (UVA-2) range rays, it's an inadequate sunscreen agent when used alone. Benzophenone-3 (oxybenzone) is used in many sunscreens and some other personal care products to protect skin from sun damage. The Journal of investigative dermatology. EltaMD. Background. While the water-soluble component may be good for using in a curly girl . Chemicals in some sunscreens that can harm marine life include: Oxybenzone, Benzophenone-1, Benzophenone-8, OD-PABA, 4-Methylbenzylidene camphor, 3-Benzylidene camphor, nano-Titanium dioxide, nano-Zinc oxide, Octinoxate, Octocrylene. Dr Perry said he thinks that people should wear sunscreen. Substituted benzophenones such as oxybenzone and dioxybenzone are used in sunscreen. Benzophenone-4 is within a group of aromatic ketones that contain both UVB and UVA absorbing properties that filter block out harmful UV rays. "Benzophenone is a suspected carcinogen, and we know that this chemical reaction causing the degradation of octocrylene is occurring in sunscreen over time," Dr. Bunick says. [Google Scholar] Experiments conducted by a research team in the U.S. and France, have shown that benzophenone seems to be formed by the degradation of a common sunscreen ingredient, octocrylene. DrugBank Accession Number. Recently, there was a study done in France looking at the conversion of sunscreens to another potential carcinogen called benzophenone that's well studied. 'Concentrations of the sunscreen agent benzophenone-3 in residents of the United States: National Health and Nutrition Examination Survey 2003-2004. Benzophenone Contamination in Sunscreens. Of all the benzophenone-type UV filters tested, benzophenone-4 (BP-4) (12) was the UV filter that tends to accumulate more among this type of compounds in placenta with concentrations between 0.25 ng/g and 5.41 ng/g [12]. A new Bloomberg report takes aim at benzophenone and octocrylene content in sunscreens, highlighting two studies published in March 2021 that found benzophenone content in commercial products.. Update (August 24, 2021): The research mentioned in the Bloomberg report has since elicited a detailed rebuttal from an author at the University Hospital of Zurich. Among the vast selection of sunscreen active ingredients, Benzophenone-3 is classified as a "chemical" sunscreen agent. Benzophenone-3 [2-hydroxy-4-methoxy-benzophenone, oxybenzophenone (BP-3)], a commonly used sunscreen agent that absorbs and dissipates ultraviolet radiation, is used in a variety of cosmetic products (Gonzalez et al. Benzophenone is a class of aromatic ketones with many derivatives. Objectives But he said that you should watch what ingredients are in the products we use. The most common sunscreens on the market contain chemical filters. Benzophenone is a known human carcinogen, and it has been discovered in popular sunscreens and after-sun care brands such as Banana Boat, Coppertone, and Neutrogena. As noted by this team of scientists, "Benzophenone is a mutagen, carcinogen, and endocrine disruptor. Under California Proposition 65, there is no safe harbor for benzophenone in any personal care products, including sunscreens, anti-aging creams, and moistu … The hormone plays a key role in the health of women, and disrupting it can lead to early puberty. Benzophenone-4 is within a group of aromatic ketones that contain both UVB and UVA absorbing properties that filter block out harmful UV rays. Environmental Health Perspective, 116(7), 893-897. A photostabilizer and sunscreen agent used for its ability to absorb UV rays. Keywords Coral Benzophenone-2 Cell toxicity Coral planula Sunscreen UV filters Introduction Benzophenone-2 (BP-2; 2,2 0,4,4 -tetrahydroxybenzophe-none, CAS No. Benzophenone-3 (BP-3) is a naturally occurring chemical found in some flowering plants. Benzophenone is an organic compound found in fruits, mainly in grapes, which is used in different pharmacological purposes, mainly in production of sunscreen. We found that oxybenzone caused high mortality . General Information. Dwella herbotech Matte Finish Sunscreen Face Serum SPF 55 PA++ with Raspberry, Carrot Seed & Avocado Oil - OIL FREE - No Parabens, Silicones, Mineral Oil, Oxide, Colour, Benzophenone - 30mL : Amazon.in: Beauty Ingredients like Oxybenzone, Benzophenone-1, Benzophenone-8, OD-PABA, 4-Methylbenzylidene camphor, 3-Benzylidene . Dr Perry said he thinks that people should wear sunscreen. Patch testing and photopatch testing was performed with benzophenone-3 and benzphenone-10 as well as with the patient's own sunscreen, which contained benzophenone-3. More often than not, Benzophenone-4 is not used as a sunscreen agent but as a photoprotectant to extend product shelf life, or as a color-protectant for products in clear packages. However, oxybenzone's toxicity mechanism (s) are not understood, hampering development of safer sunscreens. Although researchers may have differing opinions over the risk presented by such levels of benzophenone in sunscreen products, savvy consumers are likely to avoid them just the same. OCT can be synthesized by using unsubstituted benzophenone (BP), a possible human carcinogen. benzophenone was present in a wide variety of commercial sun protection factor (SPF)/sunscreen products, (2) whether benzophenone concentration in the product increased over time, and (3) if the degradation of octocrylene was the likely source for benzophenone contamination. Only sunscreens containing the UV blocker tested positive for benzophenone, and levels of the potential carcinogen increased over time in the products. Each may pose hazards to human health. Each uses a different mechanism for protecting skin and maintaining stability in sunlight. Beside the usage in sunscreens, Benzophenone-3 is incorporated in other types of cosmetic products at concentrations ranging between 0.05 - 0.5% for product protection (photoprotection). What is a benzophenone? Abstract Background The reason why patients photosensitized to the drug ketoprofen (KP) may develop severe photoallergic skin reactions to octocrylene (OCT), an organic ultraviolet filter in sunscreens and cosmetics, remains largely unknown. It helps prevent the integrity of other cosmetic ingredients from deteriorating under the sun. Benzophenone is an ingredient used in sunscreens to absorb UV radiation. Benzophenone-3 (and also other benzophenone derivatives) can cause both allergic contact dermatitis as well as photoallergic dermatitis. Benzophenone developed in increasingly high concentrations the older the product got - so buying sunscreen to use on holiday and then leaving it for a year before using it again could be harmful. No link to human cancer has been proven, but Dr Perry . 2021 Sep 20;34(9):1944-1945. doi: 10.1021/acs.chemrestox.1c00265. "This sunscreen is ideal for individuals of all ages and various skin types," says . The benzophenones are a group of aromatic ketones that have both pharmaceutical and industrial applications. Benzophenone is a mutagen, carcinogen, and endocrine disruptor. Benzophenone-3 [2-hydroxy-4-methoxy-benzophenone, oxybenzophenone (BP-3)], a commonly used sunscreen agent that absorbs and dissipates ultraviolet radiation, is used in a variety of cosmetic products (Gonzalez et al. Request PDF | The presence of benzophenone in sunscreens and cosmetics containing the organic UV filter octocrylene: A laboratory study | Background The reason why patients photosensitized to the . While the water-soluble component may be good for using in a curly girl . 131-55-5) is a chemical additive in product coatings (oil-based paints, polyurethanes), acrylic adhe-sives, plastics and personal-care products that is used to Benzophenone concentration was His research led Hawaii and other beach tourist destinations such as the U.S. Virgin Islands to ban the sale of sunscreens containing oxybenzone, which is chemically related to benzophenone and octocrylene, because of research suggesting damage to coral reefs. BP-3 absorbs and scatters the sun's harmful ultraviolet (UV) rays. Benzophenone-4. The study by Downs and colleagues reveals that benzophenone in sunscreen is formed by the degradation of octocrylene. Downs' study suggests that benzophenone was formed by degradation of octocrylene. Drug testing company, Valisure also petitioned the U.S. Food and Drug Administration to remove all sunscreen products that contain the active ingredient "octocrylene" from the . Exposing unprotected skin to UV light (primarily in the UV-B range) can result in sunburn and can promote premature aging of the skin and skin cancer. Recently, the compounds in chemical sunscreens were found to be damaging to the health of coral reefs. They are often used in sunscreens but can be found in lip balms, perfumes, nail polishes, hair sprays, dyes, and even shampoos. Research shows that benzophenone in sunscreens can interfere with estrogen, according to the WHO. Research shows that benzophenone in sunscreens can interfere with estrogen, according to the WHO. Benzophenone is a mutagen, carcinogen, and endocrine disruptor. Dr Oz: Benzophenone Sunscreen Risk. But as a report from independent laboratory Valisure revealed last week, 27 percent of the. They have UVB and some UVA absorbing properties and act like optical filters to block out harmful UV rays. As part of sunscreen products, which are OTC drugs in the United States, Benzophenone-3 (Oxybenzone) and Benzophenone-4 (Sulisobenzone) protect the skin from the harmful effects of the sun. Systemic absorption of the sunscreens benzophenone-3, octyl-methoxycinnamate, and 3-(4-methyl-benzylidene) camphor after whole-body topical application and reproductive hormone levels in humans Recent in vitro and animal studies have reported estrogen-like activity of chemicals used in sunscreen preparations. Benzophenone-3, also known as oxybenzone, is the most common benzophenone found in sunscreen products in the United States, and it is well known to cause allergic reactions after skin exposure. Janjua NR, Mogensen B, Andersson AM, et al. These products typically include a combination of two to six of these active ingredients: oxybenzone, avobenzone . We established and validated a sensitive multi-residue analytical method for identifying benzophenone (BP) and nine BP derivatives (2,4-dihydroxybenzophenone [BP-1], 2,2′,4,4′-tetrahydroxydroxybenzophenone, 2-hydroxy-4-methoxy benzophenone, 2,2′-dihydroxy 4-methoxy benzophenone, 2-hydroxybenzophenone [2-OHBP], 4-hydroxybenzophenone, 4-methylbenzophenone [4-MBP], methyl-2 . From: Analytical Profiles of Drug Substances and Excipients, 1998. Oxybenzone's safety became world news in 2018 when Hawaii became the first state to ban the sunscreen chemical. Benzophenone-8 when applied to the skin, absorbs UV rays. Reaction of the benzophenone derivative (I) with benzylmagnesium halide (II), followed by dehydration of the resulting alcohol (III), leads to the triarylethylene (IV) [8-10]. These chemicals are not listed under Proposition 65. Related terms: Flavonoid; Neoplasm; Garcinia; Sunscreen; Avobenzone . Here are a few ways to protect ourselves and marine life: Consider sunscreen without chemicals that can harm . Oxybenzone helps protect skin from the sun's harmful UV rays by absorbing UV radiation and dissipating it as heat. They found that sunscreens that contain Research shows that benzophenone in sunscreens can interfere with estrogen, according to the WHO. It is photostable and has the added benefit of stabilising the notoriously unstable UVA absorber avobenzone, meaning the two are often used in conjunction. 2006; National Library of Medicine 2007; Rastogi 2002).BP-3 also has been used as ultraviolet stabilizer in plastic surface coatings for food packaging to prevent polymer or food . The researchers tested 16 octocrylene-based sunscreen sprays and lotions purchased in France and the U.S., and all of them tested positive for benzophenone. The hormone plays a key role in the health of women and disrupting it can lead to early puberty and altered functioning of reproductive organs. Heading into the summer months, it's more important than ever to have a sunscreen on hand that you trust. But unlike mineral formulas that physically block your skin from the sun, oxybenzone is an active . Benzophenone, which is the subject of Downs and DiNardo . A Contact Dermatitis article from 2007 names BP-4 as an emerging allergen, as it was the most frequently positive chemical UV filter and third most frequently . 4 UV Pure Face and Body Physical Sunscreen SPF 47. Systemic absorption of the sunscreens benzophenone-3, octyl-methoxycinnamate, and 3-(4-methylbenzylidene) camphor after whole-body topical application and reproductive hormone levels in humans. Benzophenone. Benzophenone-1 is a chemical additive that's mostly used in nail polishes, according to the cosmetics industry web site CosmeticsInfo.org, but it also forms when the body breaks down oxybenzone . They are often used in sunscreens but can be found in lip balms, perfumes, nail polishes, hair sprays, dyes, and even shampoos. Some of the related compounds are benzophenone 1, benzophenone 2, benzophenone 3, benzophenone 4, and probably the most well known of them; oxybenzone. $29 AT AMAZON $29 AT SKINSTORE $27 AT WALMART. Benzophenone-3 (Oxybenzone) is part of the group of Environmental Phenols. But he said that you should watch what ingredients are in the products we use. Benzophenone concentration was assayed in nine commercial sunscreen products from the European Union and eight from the United States (in triplicate), including two single ingredient sources of . It said that the issue may be a manufacturing issue, rather than an ingredient one, since the benzene wasn't in all sunscreens it tested. Neutrogena Beach Defense Sunscreen Spray SPF 50 Water-Resistant Sunscreen Body Spray with Broad Spectrum SPF 50, PABA-Free, Oxybenzone-Free & Fast-Drying, Superior Sun Protection, 6.5 oz 4.7 out of 5 stars 5,866 Benzophenone-3 is used as a broad-band UV filter in concentrations of up to 10% in sunscreen products alone or in combination with other UV filters. Its presence in food products or food packaging is banned in the United States. Link between sunscreen ingredient, diet, and cancer risk investigated. Benzophenone, a common ingredient in sunscreen, has been proven as a carcinogen (cancer-causing agent) in animals. Benzophenone Derivative. Abstract. while we need more research to fully understand the consequences of benzophenone exposure through sunscreen,haereticus environmental laboratory states that "benzophenone is also an endocrine disruptor, affecting thyroid function as well as inducing anti-androgenic activity, delaying testicular development and causing anatomic difficulties with … Sunscreens that contain benzophenone-3 provide effective protection against both UVA and UVB radiation, but these preparations should not be used for young children. Derivatives of benzophenone, such as benzophenone-2 (BP2) and oxybenzone (benzophenone-3 or BP3) are common ingredients in sunscreen. Downs has been studying the health and environmental impact of sunscreens for years. Inadequate when used alone, benzophenone-3 absorbs UVB and short UVA rays but is a relatively weak chemical UV absorber. Objectives Researchers asked U.S. regulators to pull some sunscreens from the market, including brands such as Coppertone, Banana Boat and Neutrogena, saying they've found evidence of a potential . ".The recently published research paper, 'Benzophenone Accumulates Over Time from the Degradation of Octocrylene in Commercial Sunscreen Products' perpetuates misinformation and needlessly misleads and scares consumers about the safety of sunscreen products, potentially discouraging sunscreen use and putting consumers' health at risk. * Also known as Sulisobenzone. Your Reef Safe Sunscreen Guide. Is benzophenone-3 or oxybenzone in sunscreen bad for you? Similarly, recent testing of sunscreen products in US and European distribution has revealed significant levels of benzophenone, some exceeding 200 ppm. Oxybenzone is a derivative of benzophenone and a common sunscreen ingredient used in sunscreens. The substance can be found in . A popular sunscreen and anti-aging cream ingredient, Octocrylene, degrades into a toxic chemical that is a known carcinogen and endocrine disruptor. Dr Oz: Benzophenone Sunscreen Risk. No link to human cancer has been proven, but Dr Perry . For this reason, it is produced for use as sunscreen in lotions, conditioners, and cosmetics. The benzophenone derivative benzophenone-3 (BP3), also known as oxybenzone, is a common, FDA-approved active ingredient in many sunscreen products. The hormone plays a key role in the health of women, and disrupting it can lead to early puberty . Generic Name. Under California Proposition 65, there is no safe harbor for benzophenone in any personal care products, including sunscreens, anti-aging creams, and moisturizers. They may be used in a sunscreen product to reduce skin damage and to retard photodegradation or extend shelf life in toiletries and plastic surface coatings. 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